(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)lead(II)
نویسندگان
چکیده
In the title compound, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Pb(II) ion is coordinated by two N atoms from one 2,2'-bipyridine ligand and four O atoms from two 4-methyl-benzoate anions in a distorted pseudo-square-pyramidal environment, considering one of the carboxyl-ate anions as an apical ligand. Pairs of complex mol-ecules related by inversion centers are organized into dimers via pairs of Pb⋯O inter-actions [3.185 (2) Å] and stacking interactions between 2,2'-bipyridine and 4-methyl-benzoate ligands, with a mean distance between their planes of 3.491 Å.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)zinc(II)
In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H⋯O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.
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